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Structure and dynamics of the surfactant molecules in dodecyltrimethylammonium center dot poly(alpha,L-glutamate) self-assembled complexes

  1. Author:
    Zanuy, D.
    Casanovas, J.
    Aleman, C.
  2. Author Address

    Univ Politecn Catalunya, ETS Engn Ind Barcelona, Dept Engn Quim, E-08028 Barcelona, Spain. NCI Frederick, Lab Expt & Computat Biol, Ft Detrick, MD 21702 USA. Univ Lleida, Escola Univ Politecn, Dept Quim, E-25001 Lleida, Spain Aleman, C, Univ Politecn Catalunya, ETS Engn Ind Barcelona, Dept Engn Quim, Avda Diagonal 647, E-08028 Barcelona, Spain
    1. Year: 2004
    2. Date: OCT 25
  1. Journal: Chemical Physics
    1. 305
    2. 1-3
    3. Pages: 85-93
  2. Type of Article: Article
  1. Abstract:

    A molecular dynamics study has been carried out to investigate the conformational, structural and dynamical properties of the surfactant molecules in the dodecyltrimethylammonium(.)poly(alpha,L-glutamate) self-assembled complex. Simulations were performed in chloroform solution using eight different temperatures. Results indicate that the strong electrostatic interactions between the carboxylate groups of the polyelectrolyte and the positively charged trimethylammonium moieties, which are retained even at high temperatures, are responsible of the molecular organization and the low mobility of the surfactant molecules. (C) 2004 Elsevier B.V. All rights reserved

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External Sources

  1. DOI: 10.1016/j.chemphys.2004.06.034
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